Monday, September 13, 2010

Advantages and drawbacks of using non-wood fibre for papermaking

Some non-wood fibres used as raw materials for papermaking have high annual yields per hectare. The average annual yield per hectare of kenaf, a non-wood fibre, is about twice that of fast-growing softwoods (see table below) (Pierce, 1991). Non-woods have lower lignin content than woods and generally it is easier to delignify non-woods, as they have lower activation energies (Bobalek and Chaturvedi, 1989). 

Producing paper from non-wood fibres would help in reducing the need to procure pulpwood from natural forests, and for large-scale plantations. Under certain climatic conditions, non-wood fibre production may be a reasonable alternative to tree plantations. 

Average annual yields of different papermaking raw materials
Plant
Fibre yield
Pulp yield
(tonnes/year/ha)
(tonnes/year/ha)
Scandinavian softwood
1.5
0.7
Fast-growing softwood
8.6
4
Temperate softwood
3.4
1.7
Fast-growing hardwood
15
7.4
Wheat straw
4
1.9
Rice straw
3
1.2
Bagasse
9
4.2
Bamboo
4
1.6
Kenaf
15
6.5
Hemp
15
6.7
Elephant grass
12
5.7
Canary grass
8
4.0

Leading sources of non-wood fibres

At the present time, the most commonly utilized non-wood fibre is straw, which accounts for 46 percent of total production (see table below). This is followed by bagasse (14 percent) and bamboo (6 percent) (Atchison, 1995). Other non-wood fibres such as cotton, hemp, sisal and kenaf are also becoming more important in the manufacture of pulp and paper.

Leading non-wood fibres

Raw materials
Non-wood papermaking pulp capacities
1985
1988
1993
1998 (estimate)
 
('000 tonnes)
Straw
6166
5260
9566
10187
Bagasse
2339
2267
2984
3682
Bamboo
1545
1674
1316
1850
Miscellaneous: cotton, reeds, sisal, jute, hemp, abaca, kenaf, flax
3302
6366
6870
7742
Total
13352
15567
20736
23471
                                

The current situation

On a global scale, non-wood fibres are a minor part of raw material supply to paper and paperboard manufacture. In many countries, however, they are still widely used and are of significant importance in terms of overall volume and as a percentage of total pulp supply. The following table gives an idea of current use of non-wood fibres in papermaking in the 18 countries that account for nearly 98 percent of world supply:

Leading users of non-wood fibres in papermaking

Country
1993
1998 (estimate)
Non-wood pulping capacity
Percentage of total pulping capacity
Non-wood pulping capacity
Percentage of total pulping capacity

('000 tonnes)

('000 tonnes)

China
15246
86.9
16830
84.3
India
1307
55.5
2001
61.3
Pakistan
415
100
415
100
Mexico
321
29.2
324
29.3
Peru
298
95.2
296
95.2
Indonesia
267
22.1
267
10.1
Colombia
218
45.1
218
37.2
Thailand
209
100
509
100
Brazil
196
3.1
238
3.3
Venezuela
185
75.2
187
75.4
United States
179
0.3
204
0.3
Greece
150
85.7
160
84.2
Spain
140
7.9
141
7.7
Argentina
140
14.6
140
12.8
Egypt
127
100
127
100
Italy
120
13.3
120
13.3
Cuba
108
100
108
100





Turkey
103
16.5
103
16.5
Source: Oye et al., 1991.

Non-wood fibres in papermaking: A brief history

Currently, wood is by far the major raw material for the global pulp and paper industry. It is, however, a relatively new raw material in papermaking. Historically, paper was made exclusively from non-wood plant fibres. The first true production of paper is credited to T. S'ai Lun in AD 5 in China. This first paper was apparently made from textile wastes, old rags and used fishnets, which consisted of the fibres of true hemp and China grass (ramie) (Atchison and McGovern, 1993).


While non-woods were originally used for papermaking, in the late seventeenth century wood became the predominant fibre source in Europe. The seemingly inexhaustible supply and versatility of wood were the major causes of this shift. Today, most modern pulp and paper enterprises rely on wood (Smook, 1992). 

Background

Formed from wood pulp or plant fiber, paper is chiefly used for written communication. The earliest paper was papyrus, made from reeds by the ancient Egyptians. Paper was made by the Chinese in the second century, probably by a Chinese court official named Cai Lun. His paper was made from such things as tree bark and old fish netting. Recognized almost immediately as a valuable secret, it was 500 years before the Japanese acquired knowledge of the method. Papermaking was known in the Islamic world from the end of the eighth century A.D.

Knowledge of papermaking eventually moved westward, and the first European paper mill was built at Jativa, in the province of Valencia, Spain, in about 1150. By the end of the 15th century, paper mills existed in Italy, France, Germany, and England, and by the end of the 16th century, paper was being made throughout Europe.

Paper, whether produced in the modern factory or by the most careful, delicate hand methods, is made up of connected fibers. The fibers can come from a number of sources including cloth rags, cellulose fibers from plants, and, most notably, trees. The use of cloth in the process has always produced high-quality paper. Today, a large proportion of cotton and linen fibers in the mix and create many excellent papers for special uses, from wedding invitation paper stock to special paper for pen and ink drawings.


The method of making paper is essentially a simple one—mix up vegetable fibers, and cook them in hot water until the fibers are soft but not dissolved. The hot water also contains a base chemical such as lye, which softens the fibers as they are cooking. Then, pass a screen-like material through the mixture, let the water drip off and/or evaporate, and then squeeze or blot out additional water. A layer of paper is left behind. Essential to the process are the fibers, which are never totally destroyed, and, when mixed and softened, form an interlaced pattern within the paper itself. Modern papermaking methods, although significantly more complicated than the older ways, are developmental improvements rather than entirely.